Welcome, and thanks very much for the kind words. :)
I don't know much about print--at least as far as books go--but with the online print on demand stuff you can do these days that doesn't really need to stop me. I've been drawing the comic at a reasonably decent printing resolution--*I think*--since about midway through episode 10; a print collection would probably start with episode 11 at the earliest.
I feel like going to print is still a pretty long way off for A*--and it's designed primarily for a web format, rather than for print--but when people start asking me about it that starts to make me consider doing it sooner rather than later.